Electronegativity

Electronegativity is a measure of the tendency to attract electrons. Generally, it is used in the context of describing one species of atom's (element's) attraction of electrons in a chemical bond relative to another species. A higher electronegativity number indicating a greater tendency for attraction.

The Pauling scale is the first proposed and most commonly used measure of electronegativity. In this scale, Fluorine (the most electronegative element) is assigned a value of 4.0, and francium (the least electronegative) a value of 0.7. Mulliken electronegativity, Allred–Rochow electronegativity, Allen electronegativity, and Sanderson electronegativity are other ways that have been proposed to quantify this same phenomena.

Electronegativity is not strictly an atomic property however. The various methods of "measuring" electronegativity actually indicate behavior of atoms in molecules. The equivalent property of a "free atom" is termed electron affinity. It has been observed that the electronegativity of elements vary with environment. There is also a theoretical "inverse" of electronegativity, electropositivity, which is a measure of an atomic species' tendency to give up electrons to a chemical bond.

The practical effects of electronegativity can be seen in all life on Earth. The transfer of electrons between carbon (C) and oxygen (O) allows the storage and release of energy transmitted to Earth from the Sun.

"The process of photosynthesis transfers electrons from a lower to a higher potential energy (O to C). (A higher 'potential energy' because Oxygen tends to attract the electrons more strongly than Carbon...thus, work must be done to effect this transfer.)" "Cellular respiration's net effect is to transfer electrons back down to a lower (C to O) potential, thus releasing energy for use in the cell. This phenomenon can be seen in most other forms of chemical oxidation as well."

One note here, in the photosynthesis described above, Oxygen atoms can be said to undergo "Oxidation" in the sense that their electrons are drawn farther away from their nuclei. This is more a confusing semantic artifact of the definition of "oxidation" than a question of actual importance in Chemistry. The bottom line: In photosynthesis, oxygen is oxidized and Carbon is reduced. When "burning" the resulting carbohydrate, the reverse is true. The relative electronegativity of two interacting atoms also plays a major part in determining what kind of chemical bond forms between them. These types of bonds are characterized as covalent, polar, and ionic.