Vibrational spectrum

The vibrational spectrum of a mechanical system such as a molecule, crystal, or a musical instrument is the set of frequencies exhibited by regular, periodic motions of the parts of the system relative to one another that persist once excited without requiring an external driving agency. That is, the vibrational spectrum refers to free, not forced, vibration of the system.

Mechanical systems that vibrate exhibit a restoring force when displaced from their equilibrium configuration, and an inertia that causes the restoring motion to overshoot the equilibrium position, resulting in a periodic motion that normally damps out over time.

From an energy viewpoint, such systems exhibit the capacity to store potential energy in a spring-like mechanism, to convert it to kinetic energy by virtue of their motion, and to gradually return to equilibrium through some damping mechanism that dissipates the energy of vibration.